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1 article(s) from Albota, Florin

Sydnone C-4 heteroarylation with an indolizine ring via Chichibabin indolizine synthesis

Florin Albota,
Mino R. Caira,
Constantin Draghici,
Florea Dumitrascu and
Denisa E. Dumitrescu

Beilstein J. Org. Chem. 2016, 12, 2503–2510, doi:10.3762/bjoc.12.245

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Figure 1: Sydnone-pyrroloazines hybrids 1, indolizine (2), sydnone 3, indolizines attached directly to C-4 of...

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Scheme 1: Synthesis of pyridinium bromides 8 and sydnone-indolizine hybrids 9 through the Chichibabin reactio...

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Figure 2: The molecular structure of 9d with thermal ellipsoids drawn at the 50% probability level. (a) Inver...

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Figure 3: Centrosymmetric C–H···O hydrogen bonded dimeric motif in the crystal of 9d.

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Scheme 2: The synthesis and mechanism of formation of sydnone-indolizines 12.

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Figure 4: Molecular structure of 12c with atoms represented as thermal ellipsoids at the 50% probability leve...

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Figure 5: Intramolecular distortion in 12c.

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Published 23 Nov 2016

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